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تیامین هیدروکلراید دوخفا, THIAMINE HCL Duchefa , فروش تیامین هیدروکلرای دوخفا T0614


تیامین هیدروکلراید دوخفا, THIAMINE HCL Duchefa
 T0614THIAMINE HCLCAS number 67-03-8Molecular weight C12H17ClN4OS.HCl = 337.3Assay   > 98.5 %فروش تیامین
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فروش تیامین هیدروکلرای دوخفا T0614
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plant tissue culture media and biochemicals

 

 

Thiamine hydrochloride

T0614

Safety Data Sheet

according to Regulation (EU) 2015/830

Version: 2.1

Date of issue: 15/04/2011Revision date 24/01/2019

 

Supersedes 25/09/2017

 

 

 

 

SECTION 1: Identification of the substance/mixture and of the company/undertaking

 

1.1.

Product identifier

 

Product form

: Substance

Trade name

: Thiamine hydrochloride

EC-No.

 

: 200-641-8

CAS-No.

: 67-03-8

REACH registration No

: 01-2120773699-31-xxxx

Product code

: T0614

Formula

: C12H17ClN4OS · HCl

 

1.2.        Relevant identified uses of the substance or mixture and uses advised against

 

1.2.1.   Relevant identified uses

 

Main use category                                          : Professional use

 

Industrial/Professional use spec               : For professional use only. Duchefa Biochemie B.V. products are intended

 

only for "in vitro laboratory" research purposes.

 

1.2.2.   Uses advised against

 

No additional information available

 

1.3.        Details of the supplier of the safety data sheet

 

Supplier

 

Duchefa Biochemie B.V.

A. Hofmanweg 71

2031 BH Haarlem - The Netherlands

T +31(0)23-5319093 - F +31(0)23-5318027

info@duchefa.nl

 

1.4.

Emergency telephone number

 

 

Emergency number

: Supplier contact information:

 

 

+31(0)23-5319093

(M-F 09:00-17:00)

 

 

+31(0)6-30109355

(outside office hours)

 

Organisation/Company

Address

Comment

World Health Organization world

http://apps.who.int/poisoncentres/

Consult website for a local poison centre

directory of poison centres

 

 

 

SECTION 2: Hazards identification

 

2.1.

Classification of the substance or mixture

 

Classification according to Regulation (EC) No. 1272/2008 [CLP]

 

Serious eye damage/eye irritation, Category 2

H319

Full text of H statements : see section 16

 

 

Adverse physicochemical, human health and environmental effects

 

No additional information available

 

 

 

 

24/01/2019 Duchefa Biochemie B.V.                                EN (English)                                                       SDS Ref.: T0614                                               1/8

 

Thiamine hydrochloride

T0614

Safety Data Sheet

 

according to Regulation (EU) 2015/830

 

2.2.        Label elements

 

Labelling according to Regulation (EC) No. 1272/2008 [CLP]

 

 

Hazard pictograms (CLP)

 

 

 

 

 

Signal word (CLP)

 

Hazard statements (CLP)

 

Precautionary statements (CLP)

 

 

 

 

2.3.        Other hazards

 

Other hazards not contributing to the classification

 

 

:

 

 

 

 

GHS07

 

  • Warning

 

  • H319 - Causes serious eye irritation.

 

  • P280 - Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351 - IF IN EYES: Rinse cautiously with water for several minutes.

P337+P313 - If eye irritation persists: Get medical advice/attention.

 

 

  • Potential dust explosion hazard.

 

 

SECTION 3: Composition/information on ingredients

 

3.1.    Substances

 

 

Name

: Thiamine hydrochloride

CAS-No.

:

67-03-8

EC-No.

:

200-641-8

 

Name

Product identifier

%

Thiamine hydrochloride

(CAS-No.) 67-03-8

>= 98,5

 

(EC-No.) 200-641-8

 

 

Full text of H-statements: see section 16

 

3.2.        Mixtures

 

Not applicable

 

SECTION 4: First aid measures

 

4.1.        Description of first aid measures

 

 

First-aid measures general

 

First-aid measures after inhalation

 

First-aid measures after skin contact

 

First-aid measures after eye contact

 

First-aid measures after ingestion

 

 

  • If you feel unwell, seek medical advice.

 

  • Assure fresh air breathing.

 

  • Wash skin with mild soap and water.

 

  • Rinse with water

 

Remove contact lenses, if present and easy to do. Continue rinsing.

 

  • Rinse mouth out with water.

 

 

4.2.        Most important symptoms and effects, both acute and delayed

 

Symptoms/effects                                         : Gastrointestinal complaints.

 

4.3.        Indication of any immediate medical attention and special treatment needed

 

Treat symptomatically.

 

 

 

 

 

24/01/2019 Duchefa Biochemie B.V.                                EN (English)                                                       SDS Ref.: T0614                                               2/8

 

Thiamine hydrochloride

T0614

Safety Data Sheet

 

according to Regulation (EU) 2015/830

 

 

SECTION 5: Firefighting measures

5.1.

Extinguishing media

 

Suitable extinguishing media

: Water

 

 

Foam.

5.2.

Special hazards arising from the substance or mixture

Hazardous decomposition products in

: - SOx

case of fire

Corrosive vapours

 

 

Carbon oxides (CO, CO2)

 

 

- NOx.

5.3.

Advice for firefighters

 

Protection during firefighting

: Wear proper protective equipment. Self-contained breathing apparatus.

Other information

: Prevent fire fighting water from entering the environment.

SECTION 6: Accidental release measures

6.1.

Personal precautions, protective equipment and emergency procedures

6.1.1.  For non-emergency personnel

Protective equipment

: Wear suitable protective clothing.

Measures in case of dust release

: Avoid dust formation.

6.1.2.  For emergency responders

 

No additional information available

 

6.2.

Environmental precautions

 

Prevent product from entering drains.

 

6.3.

Methods and material for containment and cleaning up

Methods for cleaning up

: Sweep up, shovel or vacuum. This material and its container must be

 

 

disposed of in a safe way, and as per local legislation.

6.4.

Reference to other sections

 

Reference to other sections (8, 13).

 

SECTION 7: Handling and storage

 

7.1.        Precautions for safe handling

 

No additional information available

 

7.2.        Conditions for safe storage, including any incompatibilities

 

Storage conditions                                        : Keep container tightly closed and dry

 

Store at room temperature.

 

7.3.        Specific end use(s)

 

For professional use only. Duchefa Biochemie B.V. products are intended only for "in vitro laboratory" research purposes.

 

SECTION 8: Exposure controls/personal protection

 

8.1.        Control parameters

 

No additional information available

 

8.2.        Exposure controls

 

 

 

24/01/2019 Duchefa Biochemie B.V.                                EN (English)                                                       SDS Ref.: T0614                                               3/8

 

Thiamine hydrochloride

 

 

 

T0614

Safety Data Sheet

 

 

 

 

according to Regulation (EU) 2015/830

 

 

 

 

 

 

 

 

 

 

 

Hand protection:

 

 

 

 

 

 

 

 

 

 

 

 

Type

 

Material

Permeation

Thickness (mm)

Standard

 

 

 

 

 

 

 

 

Gloves

 

Nitrile rubber (NBR)

6 (> 480 minutes)

0,11

EN 374

 

 

 

 

 

 

 

 

 

Eye protection:

 

Safety glasses (to European standard EN 166 or equivalent)

 

Skin and body protection:

 

Long sleeved protective clothing

 

Respiratory protection:

 

Dust production: dust mask with filter type P1

 

SECTION 9: Physical and chemical properties

 

9.1.        Information on basic physical and chemical properties

 

Physical state

: Solid

Appearance

: Powder.

Molecular mass

: 337,3 g/mol

Colour

 

: White to off-white.

Odour

 

: Characteristic.

Odour threshold

: No data available

pH

 

: 2,7 - 3,3 (2,5%)

Relative evaporation rate (butylacetate=1)

: No data available

Melting point

: 248 - 250 °C

Freezing point

: No data available

Boiling point

: No data available

Flash point

: No data available

Auto-ignition temperature

: No data available

Decomposition temperature

: No data available

Flammability (solid, gas)

: No data available

Vapour pressure

: No data available

Relative vapour density at 20 °C

: No data available

Relative density

: 0,4 g/cm3

Solubility

: Readily soluble in water.

 

 

Water: ≈ 1000 g/l

Log Pow

: No data available

Viscosity, kinematic

: No data available

Viscosity, dynamic

: No data available

Explosive properties

: No data available

Oxidising properties

: No data available

Explosive limits

: No data available

9.2.

Other information

 

 

No additional information available

 

 

 

 

 

 

24/01/2019 Duchefa Biochemie B.V.                                EN (English)                                                       SDS Ref.: T0614                                               4/8

 

Thiamine hydrochloride

T0614

Safety Data Sheet

 

according to Regulation (EU) 2015/830

 

 

SECTION 10: Stability and reactivity

 

10.1.    Reactivity

 

Stable under normal conditions.

 

10.2.     Chemical stability

 

Stable under normal conditions.

 

10.3.    Possibility of hazardous reactions

 

Potential dust explosion hazard.

 

10.4.    Conditions to avoid

 

- Heat

 

Water, humidity.

 

10.5.    Incompatible materials

 

Bases

 

  • Metals Oxidising agents.

 

10.6.    Hazardous decomposition products

 

Hydrogen chloride

 

Nitrogen oxides

 

- SOx.

 

SECTION 11: Toxicological information

 

11.1.

Information on toxicological effects

Acute toxicity

: Not classified

 

 

 

Thiamine hydrochloride (67-03-8)

 

 

 

 

 

LD50 oral rat

 

3710 mg/kg

LD50 oral

 

8224 mg/kg (mouse)

Skin corrosion/irritation

: Slightly irritating to the skin

 

 

 

pH: 2,7 - 3,3 (2,5%)

Serious eye damage/irritation

: May cause eye irritation.

 

 

 

pH: 2,7 - 3,3 (2,5%)

Respiratory or skin sensitisation

: Not classified

Germ cell mutagenicity

: Not classified

Carcinogenicity

: Not classified

Reproductive toxicity

: Not classified

STOT-single exposure

: Not classified

STOT-repeated exposure

: Not classified

Aspiration hazard

: Not classified

Other information

: See actual entry in RTECS for complete information: XI7350000.

SECTION 12: Ecological information

12.1.

Toxicity

 

 

 

 

 

24/01/2019 Duchefa Biochemie B.V.                                EN (English)                                                       SDS Ref.: T0614                                               5/8

 

Thiamine hydrochloride

T0614

Safety Data Sheet

 

 

according to Regulation (EU) 2015/830

 

 

 

 

 

 

 

 

 

 

 

Thiamine hydrochloride (67-03-8)

 

 

 

LC50 fish 1

> 100 mg/l Oncorhynchus mykiss (Rainbow trout)

 

 

EC50 Daphnia 1

> 100 mg/l (Daphnia Magna)

 

12.2.

Persistence and degradability

 

 

 

 

 

 

 

Thiamine hydrochloride (67-03-8)

 

 

 

Persistence and degradability

Product is biodegradable.

 

 

Biodegradation

74 % (7d)

 

12.3.

Bioaccumulative potential

 

 

 

No additional information available

 

 

12.4.

Mobility in soil

 

 

 

No additional information available

 

 

     

 

12.5.    results of PBT and vPvB assessment

 

No additional information available

 

12.6.    Other adverse effects

 

No additional information available

 

SECTION 13: Disposal considerations

 

13.1.

Waste treatment methods

 

 

Waste treatment methods

: This product is not hazardous.

 

Sewage disposal recommendations

: Disposal must be done according to official regulations.

Product/Packaging disposal

: When not empty dispose of this container at hazardous or special waste

recommendations

collection point.

 

Ecology - waste materials

: Avoid release to the environment.

 

SECTION 14: Transport information

 

In accordance with ADR / IATA / IMDG

 

 

 

 

 

 

ADR

 

IMDG

IATA

14.1.

UN number

 

 

Not applicable

Not applicable

Not applicable

 

 

 

 

14.2.

UN proper shipping name

 

 

Not applicable

Not applicable

Not applicable

 

 

 

Not applicable

Not applicable

Not applicable

 

 

 

 

14.3.

Transport hazard class(es)

 

 

Not applicable

Not applicable

Not applicable

 

 

 

Not applicable

Not applicable

Not applicable

 

 

 

 

14.4.

Packing group

 

 

Not applicable

Not applicable

Not applicable

 

 

 

 

14.5.

Environmental hazards

 

 

Not applicable

Not applicable

Not applicable

 

 

 

 

No supplementary information available

 

 

 

 

 

 

 

24/01/2019 Duchefa Biochemie B.V.                                EN (English)                                                       SDS Ref.: T0614                                               6/8

 

Thiamine hydrochloride

T0614

Safety Data Sheet

 

according to Regulation (EU) 2015/830

 

 

14.6.    Special precautions for user

 

  • Overland transport Not applicable

 

  • Transport by sea Not applicable

 

  • Air transport

 

Not applicable

 

14.7.     Transport in bulk according to Annex II of Marpol and the IBC Code

 

Not applicable

 

SECTION 15: Regulatory information

 

15.1.    Safety, health and environmental regulations/legislation specific for the substance or mixture

 

15.1.1. EU-Regulations

 

No REACH Annex XVII restrictions

 

Thiamine hydrochloride is not on the REACH Candidate List

 

Thiamine hydrochloride is not on the REACH Annex XIV List

 

15.1.2. National regulations

 

Germany

 

 

Reference to AwSV

 

 

 

12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV

 

 

  • Water hazard class (WGK) 1, Slightly hazardous to water (Classification according to VwVwS, Annex 3; ID No. 3924)

 

  • Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)

 

 

Netherlands

 

SZW-lijst van kankerverwekkende stoffen                                                                         : The substance is not listed

 

SZW-lijst van mutagene stoffen                                                                                            : The substance is not listed

 

NIET-limitatieve lijst van voor de voortplanting giftige stoffen – Borstvoeding  : The substance is not listed

 

NIET-limitatieve lijst van voor de voortplanting giftige stoffen –                               : The substance is not listed

 

Vruchtbaarheid

 

NIET-limitatieve lijst van voor de voortplanting giftige stoffen – Ontwikkeling    : The substance is not listed

 

15.2.    Chemical safety assessment

 

No additional information available

 

SECTION 16: Other information

 

Indication of changes:

 

1.1

REACH registration No

Added

 

2.1

Classification according to Regulation

Added

Change from no classification to

 

(EC) No. 1272/2008 [CLP]

 

H319 (Eye cat.2) based on new

 

 

 

data from manufacturer.

2.2

Hazard pictograms (CLP)

Added

GHS07

2.2

Signal word (CLP)

Added

Warning

2.2

Precautionary statements (CLP)

Added

P280;P305+P351;P337+P313

 

 

24/01/2019 Duchefa Biochemie B.V.                                EN (English)                                                       SDS Ref.: T0614                                               7/8

 

Thiamine hydrochloride

T0614

Safety Data Sheet

 

 

according to Regulation (EU) 2015/830

 

 

 

 

 

 

 

 

Abbreviations and acronyms:

 

 

 

ATE

Acute Toxicity Estimate

 

 

 

ADR

European Agreement concerning the International Carriage of Dangerous Goods by Road

 

 

 

BCF

Bioconcentration factor

 

 

 

CLP

Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008

 

 

 

DPD

Dangerous Preparations Directive 1999/45/EC

 

 

 

DSD

Dangerous Substances Directive 67/548/EEC

 

 

 

IATA

International Air Transport Association

 

 

 

IMDG

International Maritime Dangerous Goods

 

 

 

LC50

Median lethal concentration

 

 

 

LD50

Median lethal dose

 

 

 

LOAEL

Lowest Observed Adverse Effect Level

 

 

 

NOAEC

No-Observed Adverse Effect Concentration

 

 

 

PBT

Persistent Bioaccumulative Toxic

 

 

 

REACH

Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation (EC) No 1907/2006

 

 

SDS

Safety Data Sheet

 

 

 

Data sources

: REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT

 

 

AND OF THE COUNCIL of 16 December 2008 on classification, labelling

 

 

and packaging of substances and mixtures, amending and repealing

 

 

Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No

 

 

1907/2006. Supplier.

 

 

 

Full text of H- and EUH-statements:

 

Eye Irrit. 2

Serious eye damage/eye irritation, Category 2

H319

Causes serious eye irritation.

 

SDS Biochemicals version 2019

 

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

24/01/2019 Duchefa Biochemie B.V.                                EN (English)                                                       SDS Ref.: T0614                                               8/8

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