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سدیم بوروهیدرید(سدیم بورهیدرید) مرک آلمان 25 گرمی کد 806372 Sodium borohydride


مشخصات محصول

مشخصات محصول

 

Key Spec Table

CAS #EC NumberHill FormulaChemical FormulaMolar Mass
16940-66-2241-004-4H₄BNaNaBH₄37.83 g/mol

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Catalogue Number806372
SynonymsSodium tetrahydridoborate
Product Information
CAS number16940-66-2
EC number241-004-4
Hill FormulaH₄BNa
Chemical formulaNaBH₄
Molar Mass37.83 g/mol
HS Code2850 00 20
Applications
ApplicationSodium borohydride for analysis. CAS No. 16940-66-2, EC Number 241-004-4.
Physicochemical Information
Boiling point500 °C (decomposition)
Density1.07 g/cm3 (20 °C)
Explosion limit 3.02 %(V)
Flash point69 °C not applicable
Ignition temperature220 °C
Melting Point>360 °C (slow decomposition)
pH value11 (10 g/l, H₂O, 20 °C)
Vapor pressure<1 hPa (25 °C)
Bulk density350 - 500 kg/m3
Toxicological Information
LD 50 oralLD50 Rat 160 mg/kg
LD 50 dermalLD50 Rabbit 230 mg/kg
Safety Information according to GHS
Hazard Pictogram(s)



Hazard Statement(s)H360FD: May damage fertility. May damage the unborn child.
H260: In contact with water releases flammable gases which may ignite spontaneously.
H301: Toxic if swallowed.
H314: Causes severe skin burns and eye damage.
EUH014: Reacts violently with water.
Precautionary Statement(s)P201: Obtain special instructions before use.
P280: Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P310: IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician.
P402 + P404: Store in a dry place. Store in a closed container.
RTECSED3325000
Storage class4.3 Hazardous materials, which set free flammable gases upon contact with water
WGKWGK 2 water endangering
Disposal26
Alkali and alkaline-earth metals should be taken up in an inert solvent and neutralized by adding 2-propanol (Cat. No. 100995) drop wise with stirring. Should the reaction be more violent than expected, conversion should be carried out with tert-butanol or octanol. Caution: This reaction produces hydrogen, which can form explosive mixtures; take necessary precautions. When the reaction has ceased, add water drop wise; neutralize; container D. In the case of alkali or alkaline-earth borohydrides, add methanol (Cat. No. 106008) with stirring; in the case of alkali or alkaline-earth amides and hydrides, organoaluminium and organotin hydrides, add 2-propanol (Cat. No. 100995) drop wise. The substances, which are usually in solid form, should be previously suspended in an ether! When the respective reaction has ceased, hydrolize with water; then neutralize. Container D or E. Lithium aluminium hydride must also be destroyed by slurrying in an ether. Under an inert gas and with thorough stirring, add drop wise a 1:4 mixture of ethyl acetate (Cat. No. 822277) and the ether used to prepare the slurry. Always ensure thorough mixing (stirring)! Container A.
Safety Information
Hazard SymbolsToxic
Flammable
Corrosive
Categories of dangerhighly flammable, toxic, corrosive
R PhraseR 60-61-25-14/15-34
May impair fertility.May cause harm to the unborn child.Also toxic if swallowed.Reacts violently with water, liberating extremely flammable gases.Causes burns.
S PhraseS 14-26-36/37/39-43-45-53
Keep away from oxidising and acidic substances as well as heavy-metal compounds.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of fire, use sand. Never use water.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).Avoid exposure - obtain special instructions before use.
Storage and Shipping Information
StorageStorage temperature: no restrictions.
Transport Information
Declaration (railroad and road) ADR, RIDUN 1426, 4.3, I
Declaration (transport by air) IATA-DGRUN 1426, 4.3, I
Declaration (transport by sea) IMDG-CodeUN 1426, 4.3, I
Specifications
Assay (oxidimetric)≥ 96.0 %
Identitypasses test
Chloride (Cl)≤ 0.5 %
Sulphate (SO₄)≤ 0.005 %
Heavy metals (as Pb)≤ 0.005 %
As (Arsenic)≤ 0.001 %
Bi (Bismuth)≤ 0.0005 %
Fe (Iron)≤ 0.005 %
Hg (Mercury)≤ 0.00001 %
Sb (Antimony)≤ 0.005 %
Se (Selenium)≤ 0.0002 %
نمودار تغییر قیمت
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